In a flaming cocktail, the alcohol gives off vapors which rise upward, off the drink, where they can then be ignited. These work slightly differently, based on the type of alcohol used.
Background: Abbi Hance-Briscoe (WFAA). Inset: The “Flaming Pineapple” drink at Twisted Trick (WFAA). A Texas couple never thought their summertime date would end with a trip to the local burn ...